option B
tan-1\(\sqrt{3}\) = \(\frac { π }{ 3 }\)
and sec-1(-2) = π – \(\frac { π }{ 3 }\) = \(\frac { 2π }{ 3 }\),
since principal value branch of sec-1 is [0, π] – {\(\frac { π }{ 2 }\)}
∴ tan-1\(\sqrt{3}\) – sec-1(-2) = \(\frac { π }{ 3 }\) – \(\frac { 2π }{ 3 }\)
= – \(\frac { π }{ 3 }\)